1.

(a) What type of isomerism is shown by the complex [Co(NH3)5(SCN)]2+? (b) Why is [NiCl4]2− paramagnetic while [Ni(CN)4]2− is diamagnetic? (Atomic number of Ni = 28) (c) Why are low spin tetrahedral complexes rarely observed?

Answer» (a) What type of isomerism is shown by the complex [Co(NH3)5(SCN)]2+?
(b) Why is [NiCl4]2 paramagnetic while [Ni(CN)4]2 is diamagnetic? (Atomic number of Ni = 28)
(c) Why are low spin tetrahedral complexes rarely observed?


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