1.

Account for the following:Bond dissociation energy of F_2 is less than that of Cl_2.

Answer»

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Solution :Bond dissociation ENERGY of ` F_2` is less than that of `Cl_2` due to inter electronic repulsions in small size FLUORINE atoms. Chlorine has a large value of bond dissociation energy because of the possibility of multiple `p pi - dpi ` back BONDING involving filled p-orbitals and the vacant d-orbital.


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