1.

Account for the following (i) CI – CH_2COOH is a stronger acid than CH_3COOH(ii) Carboxylic acids do not give reactions of carbonyl group.

Answer»

Solution : (i) Monochloroacetic acid is comparatively stronger acid than acetic acid. This is due to -CI as a -I GROUP
(ii) CARBOXYLIC acids do not give REACTIONS of carbonyl group because the lone pair of electrons on the oxygen attached to HYDROGEN in the – COOH group are involved in resonance, which makes the carbon less electrophilic.


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