1.

Addition of excess aqueous ammonia to a pink coloured aqueous solution ofandgives an octahedral complex Y in the presence of air .In aqueous solution, complex Y behaves as 1:3 electrolyte . The reaction of X with excess HCl at room temperature results in the formation of a blue coloured complex Z. The calculated spin only magnetic moment of X and Z is 3.87 B.M whereas it is zero for complex Y. Among the following options , which statement(s) is(are) correct ?

Answer»

The hybridisation of the central metal ion in Y is `d^(2)sp^(3)`
Addition of silver NITRATE to Y gives only two equivalents of silver chloride
When X and Z are in equilibrium at `0^(@)`C , the colour of the solution is pink
Z is a TETRAHEDRAL complex.

Solution :


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