1.

Addition of excess aqueous ammonia to a pink coloured aqueous solution of MCl_(2).6H_(2)O (X) and NH_(4)Cl gives an octahedral complex Y in the pressure of air. In aqueous solution, complex Y behaves as 1 : 3 electrolyte. The reaction of X with excess HCl at room temperature results in the formation of a blue coloured compelx Z. The calculated spin only magnetic moment of X and Z is 3.87 B.M., whereas it is zero for complex Y. Among the following options, which statement(s) is(are) correct ?

Answer»

The hybridization of the central metal ion in Y id `d^(2)sp^(3)`
Addition of silver nitrate to Y gives only two equivalents of silver CHLORIDE
When X and Z are in equilbrium at `0^(@)C`, the COLOURED of the solution is PINK
Z is a tetrahedral complex

Answer :A::C::D


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