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Adolfvon Beeyersuggestedthat,sincecarbonprefers tohavetetradralgeometrv wih bondanglesof approximately109^(@)ring sizesotherthanfiveand six may betoostrainedto exist ,Baeyer based hishypothesison thesimplegeometricalnationthata three-memberedring ( cyclopropane ) shouldbe anequilatera trianglewithbond anglesto 60^(@) a fourmembered ring (cyclobutane) shouldbe asquarewithbondanglesof 90^(@) and so on . Accordingto Beayer'sanalysiscyclopropane, witha bondablecompressionof 109^(@)-60^(@)=49^(@) , shouldhavea large amountof anglestrainand mustthereforebehighlyreactive cyclohexane becomes puckeredtoreeveitsstrainthe angulardeviation ofcycloalkaneis (-11^(@)) , Greater is the angulardeviationmore is thetorsinalstrain . thetendency ofCyclopropropane (i) cyclobutane (ii) andcyclopentane (iii)to firm additioncompounds is intheorder: |
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Answer» IgtIIgtIII |
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