1.

Adsorption of a gas on the surface of solid is generally accompanied by decrease in entropy. Still it is a spontaneous process. Explain.

Answer»

Solution :WHETHER or not, a process occurs, is decided by `DeltaG ` value which should be NEGATIVE. In ADSORPTION, `DeltaS` is -ve, but `DeltaH ` is also -ve because it is an EXOTHERMIC process.
`DeltaG=DeltaH-TDeltaS`
The NET value of `DeltaG` is negative. Hence, it is a spontaneous process.


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