1.

Ag_((s))|Ag_((aq))^(+)(0.01M)||Ag_((aq))^(+)(0.1M)|Ag_((s))E_(Ag_((s))//Ag_((aq)))^(@)=0.80volt

Answer»

CELL cannot function as anode and cathode are of same MATERIAL
`E_(cell)=0.0592V`
`E_(cell)=0.80V`
`E_(cell)=0.0296V`

Solution :For an electrolytic concentration cell,
`E_(cell)=(0.0591)/(n)"LOG"(C_(1)(R.H.S.))/(C_(2)(L.H.S.))`
`=(0.0591)/(1)"log"(0.1)/(0.01)=0.0591log10=0.0591V`.


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