1.

Aliphatic nucleophilic substitution is mainly of two type S_(N^(1))" and "S_(N^(2)) . S_(N^(2)) reaction proceed with strong nucleophile in polar aprotic solvent. 3^(@) halides do not give S_(N^(2)) reaction. Inverted products are obtained in this reaction and mechanism of reaction occurs through the formation of transition state. S_(N^(1)) reaction proceed through the formation of carbocation in polar aprotic solvent. Solvent itself acts as nucleophile in this reaction. Racemization takes place in S_(N^(1)) reaction. Which of the following compounds will give S_(N^(1)) reaction ?

Answer»

`Ph-OVERSET(CH_(3))overset(|)underset(Cl)underset(|)C-CH_(2)CH_(3)`
`H_(3)C-Cl`
`H_(3)C-CH_(2)-Br`

SOLUTION :N//A


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