1.

Aliphatic nucleophilic substitution is mainly of two type S_(N^(1))" and "S_(N^(2)) . S_(N^(2)) reaction proceed with strong nucleophile in polar aprotic solvent. 3^(@) halides do not give S_(N^(2)) reaction. Inverted products are obtained in this reaction and mechanism of reaction occurs through the formation of transition state. S_(N^(1)) reaction proceed through the formation of carbocation in polar aprotic solvent. Solvent itself acts as nucleophile in this reaction. Racemization takes place in S_(N^(1)) reaction. Which one of the following will give S_(N^(2)) reaction?

Answer»

`H_(3)C-overset(CH_(3))overset(|)UNDERSET(CH_(3))underset(|)C-Cl`


`H_(2)C=CH-Cl`

Solution :N//A


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