1.

Aliphatic nucleophilic substitution mainly takes place by two mechanisms (i.e) SN^1 & SN^2Primary halides mainly undergo by SN^2mechanism and are favourable in polar aprotic solvents. SN^1 reactions takes place mainly by tertiary halide and are more favourable in polar protic solvents, In case of tertiary halides, E_1comes competition to SN^1 reaction. Keeping in view of these general points, answer the following questions(+)C_6H_5CH(CH_3)Cl to (pm) C_6H_5CH(OH)CH_3in which of the following solvents, the above reaction is most favourable

Answer»

75% WATER + 25% `CH_3OH`
25% water + 75% methanol
100% methanol
10% water + 90% methanol

Solution :Given reaction follows `SN^1` mechanism, which TAKES PLACE favorable in polar solvents due to FORMATION of cation is the intermediate step


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