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Alkyl halides can participate in both S_(N^(1)) and S_(N^(2)) reactions depending upon their anture and conditions. The reactivity order in the three types of alkyl halides is the reverse in S_(N^(1)) reactions than what we observe in S_(N^(2)) reactions. Apart from that, there is inversion of configuration in case of alkyl halides when they participate in S_(N^(2)) reactions. on the other hand, partial or complete racemisation occurs in S_(N^(1)) reactions. Q. S_(N^(1)) reactions take place much more rapidly in polar solvents than in non-polar solvents. this is because of hydration of nucleophile. |
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Answer» by the electron rich oxygen atoms of solvent `(H_(2)O)` molecules. |
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