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All aliphatic amines are more basic than ammonia but due to delocalisation of lone pair of electrons of the nitrogen atom on the benzene ring, aniline is a weaker base than ammonia. The basic strength of the substituted anilines, however, depends upon the nature of the substituent whereas electron donating group tend to increase, electron-with drawing groups tend to decrease the basic strength. The base trengthening effect of the electron-donating group and the base weaken effect of the electron withdrawing group is, however, more pronouned at p-than at m-position. However due to ortho effect, o-substituted anilines are weaker bases than anilines regardless of the nature of substituent whether electron-donating or electron withdrawing. Choose among the following amines the correct decreasing order of their basic strength |
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Answer» `I GT II gt III gt IV` |
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