1.

An antifreeze solution is prepared from 2226 g of ethylene glycol,C2H4(OH2 and 200 g of water. Calculate the molality of the solution. If thedensity of the solution is 1-072 gmL-1, then what shall be the molarity ofthe solution ?

Answer»

Calculation of Molality :

Mass of ethylene glycol = 222.6 (Given)

Molar mass of ethylene glycol [C2H4(OH)2]

= 2 X 12 + 6 x 1 + 2 x 16

= 62

Therefore moles of ethylene glycol

= 222.6g/62 gmol-1

= 3.59 mol

Mass of water = 200g (Given)

Therefore molality of the solution is = (moles of ethylene glycol/mass of water) x 1000

= (3.59/200) x 1000

= 17.95 m

Calculation of Molarity:

Moles of ethylene glycol = 3.59 mol (already calculated)

Total Mass of solution = 200 + 222.6

= 422.6g

Volume of solution = mass / density volume

= 422.6/1.072

= 394.22 ml

now molarity of the solution is = (moles of ethylene glycol/volume of solution) x 1000

= (3.59/394.22) x 1000

= 9.11 M



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