1.

Arrange the following compounds in the decreasing order of their solubility in water :(a) Ethyl amine, diethyl amine and triethyl amine.(b) Ethyl amine, n-propyl amine and n-butyl amine.(c) n-Butane, n -butyl alcohol and n-butyl amine.

Answer»

(a) Ethyl amine, diethyl amine and triethyl amine :

Diethyl amine > triethyl amine > ethyl amine 

(The reason that ethyl group has greater +1 effect than methyl group)

(b) Ethyl amine, n-propyl amine and n-butyl amine :

n-butyl amine < n-propyl amine < ethyl amine

(c) n-Butane, n -butyl alcohol and n-butyl amine :

n-butyl alcohol < n-butyl amine < n-butane



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