1.

At 33K. N2H4 is fifty percent dissociated. Calculate the standard free energy change at this temperature and at one atmosphere.

Answer»

T = 33K 

N2O4 ⇌ 2NO2 

Initial concentration 100% 

Concentration dissociated 50% 

Concentration remaining at equilibrium 50% – 100%

Keq = 100/50 = 2 

∆G° = -2.303 RT log Keq 

∆G° = -2.303 x 8.31 x 33 x log 2 

∆G° = -190.18 J mol-1



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