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At very high pressure, the van der Waals equation reduces toA. `PV =RT -a//V`B. `PV =RT +Pb`C. `PV =RT`D. `PV =RT -a//V^(2)` |
Answer» At high `P` the pressure correction is negligible as compared to total pressure `[P+(an.^(2))/(V^(2))](V-nb)=nRTas (an.^(2))/(V^(2)) lt lt lt P` `:.` For 1 mole of gas `P(V-b) =RT` `PV =RT +Pb` . |
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