1.

Bond dissociation enthalpy of `H_(2)` , `Cl_(2)` and `HCl` are `434, 242` and `431KJmol^(-1)` respectively. Enthalpy of formation of `HCl` isA. `93 kJ mol^(-1)`B. `-245 kJ mol^(-1)`C. `-93 kJ mol^(-1)`D. `+245 kJ mol^(-1)`

Answer» Correct Answer - C
`(1)/(2)H_(2)(g)+(1)/(2)Cl_(2)(g)toHCl(g)`, `DeltaH^(@)=?`
`Delta_(r )H^(@)=(1)/(2)BE(H_(2))+(1)/(2)BE(Cl_(2))-BE(HCl)`
`=(1)(2)(434)+(1)/(2)(242)-431`
`=217+121-431=-93 kJ mol^(-1)`


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