1.

Calculate the enthalpy of combustion of ethylene at 300 K at constant pressure, If Its heat of combustion at constant volume (∆U) is – 1406 KJ.

Answer»

The complete ethylene combustion reaction can be written as,

C2H4(g) + 3O2(g) → 2CO2(g) + 2H2O(I) 

∆U = -1406 kJ 

∆n = np(g) – nr(g) 

∆n = 2 – 4 = -2 

∆H = U + RT ∆n(g)

∆H = -1406 + (8.314 x 10-3 x 300 x (-2)) 

∆H = – 1410.9 kJ



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