1.

Calculate the equilibrium constant `K_(p)` and `K_(c )` for the reaction: `CO(g)+1//2O_(2)(g) hArr CO_(2)(g)`. Given that the partial pressure at equilibrium in a vessel at `3000 K` are `p_(CO)=0.4 atm, p_(CO_(2))=0.2 atm`

Answer» Correct Answer - B
`CO(g)+1/2O_(2)(g)hArr CO_(2)(g)`
`K_(p)=([p_(CO_(2))(g)])/([p_(CO)(g)][p_(O_(2))(g)]^(1//2))`
`=0.6/(0.4xx(0.2)^(1//2))=0.6/(0.4xx0.4472)=3.356 "atm"^(-1//2)`
`K_(p)=K_(c )(RT)^(Deltan)`
`Deltan=1-(1+1/2)=-1/2`
`K_(c )=K_(p)/((RT)^(Deltan))`
`=3.356/((0.082xx3000)^(-1//2))`
`=3.356xx(0.082xx3000)^(1//2)`
`=3.356xx15.684=52.67`


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