1.

Calculate the mean bond enthalpy of C-H bond in methane.

Answer»

CH4 (g) → C (g) + 4H(g), ΔH = ?

Mean bond enthalpy of C-H bond

\(\frac{1}{4}\) x Heat energy required to break four C-H bonds in CH4 (g)

\(\frac{1}{4}\) x ΔH

The ΔH for the reaction, CH4 (g) → C (g) + 4H (g) is the enthalpy of atomisation of methane

ΔH = ΔH1 + ΔH2 + ΔH3 + ΔH4

= (425 + 470 + 416 + 336) kJ mol-1

= 1647 kJ mol-1

Mean bond enthalpy of C-H bond in CH4 (g)

\(\frac{1}{4}\) x ΔH = \(\frac{1}{4}\) x 1647 kJ/mol

= 411.7 kJ mol-1



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