1.

[Co (H_(2) O) _(6)]Cl_(3) overset(NH_(3)) to A+B+C A, B and C are complexs with different coordination entity without any H_(2)O molecule. Among these C shows two different spatial arrangements one is green and another is violet complex respectively. Colour of A and B complexes are yellow & purple respectively. Then which of the following statement is CORRECT ?

Answer»

Aqueous solution of YELLOW complex shows Vant hoff factor (i) = 3 in COLLIGATIVE properties.
One mole of GREEN complex produces one mole AgCl on reaction with `aGno_(3)`
Green and violet complexes are optical ISOMER respectively.
Yellow and purple are geometrical ISOMERS to each other.

Solution :`[Co(CN_(3)) _(6)] Cl_(5):` yellow
`[Co(NH_(5)) _(5) Cl] Cl_(2):` purple
cis : `[Co (NH_(3)) _(4) Cl_(2)]Cl :` violet
trans : `[Co (NH_(5)) _(4) Cl_(2) ] Cl :` green


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