1.

Co-ordiantion compounds show structural isomerism and it is different from the nature of the isomerism which we generally come across in organic compounds. The co-ordination and linkage isomers depending upon their upon the number of ions which they furnish upon dissociation in aqueous solution . The isomers belonging to a particular type can also be distinguished from each structural isomerism, the co-ordination compounds are also involved in geometrical and optical isomerism. Whereas optical octahedral and square planar complexes can exhibit geometrical isomerism. Which of the following will not show geometrical isomerism ?

Answer»

`[Cr(NH_(3))_(4)Cl_(2)]Cl`
`[CoCl_(2)(en)_(2)]Cl`
`[Co(NH_(3))_(5)NO_(2)]Cl_(2)`
`[PT(NH_(3))_(2).Cl_(2)]`

Solution :Octahedral complexes of the type `MA_(5)B` do not show any geometrical ISOMERISM.


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