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Colligative property measurement is one of the techniques used in the measurement of chemical quantitates with reasonably accuracy. If a 40.65 gm sample of K2SO4 and BaSO4 is dissolved in 900 gm of pure water to form a solution ‘A’ at 57∘C, its vapour pressure is found to be 39.6 torr while vapour pressure of pure water at 57∘C is 40 torr. Density of solution A is 1.24 g/ml. In a different experiment when small amount of pure BaSO4 is mixed with water at 57∘C it gives the osmotic rise of 4.05×10−5 atm. (r = 0.082 Lt-atom/mol - K ; K = 39, Ba = 137, S = 32, O = 16) Percentage of K2SO4 in the sample is

Answer»

Colligative property measurement is one of the techniques used in the measurement of chemical quantitates with reasonably accuracy.

If a 40.65 gm sample of K2SO4 and BaSO4 is dissolved in 900 gm of pure water to form a solution ‘A’ at 57C, its vapour pressure is found to be 39.6 torr while vapour pressure of pure water at 57C is 40 torr. Density of solution A is 1.24 g/ml. In a different experiment when small amount of pure BaSO4 is mixed with water at 57C it gives the osmotic rise of 4.05×105 atm. (r = 0.082 Lt-atom/mol - K ; K = 39, Ba = 137, S = 32, O = 16)

Percentage of K2SO4 in the sample is




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