1.

Column-I and Column-II contains four entries each. Entries of Column -I are to be matched with some entries of Column-II. One or more than one entries of Column-I may have the matching with the same entries of Column-II.

Answer»


Solution :
`toSi-O-Si=144^(@)`
`to`Hybridization of O-atom changed to `sp^(2)`
`to` In `2p_(pi)-3d_(pi)` back bonding non-axial d-orbital of `t_(2g)` is used
`to`Electron density at O-atom decrease
(b)
`toangleCl-O-Cl` increase due to back bonding and steric repulsion between both Cl-atoms
`to` Hybridization of C remains `sp^(2)`
`to` Electron density increase at central C-atom.
(c)
`to` Electron density at Si-atom increase due to `2p_(pi)-3d_(pi)` back bonding
`to` Non-axial d-orbital of `t_(2g)` set of orbitals is involved in back bonding
`to` All `O-Si-O` remains at `109^(@)28.` because all FOUR substituents are same
(d)
`to` hybridization of central does not change.
`to` Electron density at B-atom increase
`to` All `N-B-N` remain same as all three substituentare same.


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