1.

{:("COLUMN-I(Molecule)","COLUMN-II(Bond Angle)"),("A)" BF_(3),"p)" 88^(@)),("B)" NF_(3),"q)" 96^(@)),("C)" PF_(3),"r)" 103^(@)),("D)" ClF_(3),"s)" 120^(@)):}

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Solution :Bond angle
`{:("a)"BF_(3) rarr 120^(@) (sp^(2) hy),"b)" NH_(3) rarr 103^(@) (sp^(3)) "LP-BP repulsion",),("C)" PF_(3) rarr 96^(@)(sp^(3))"same as","d)" CIF_(3) rarr 88^(@)(sp^(3)d) "same as",):}`


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