1.

Complete the following equations: CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-O-CH_(3)+HI to

Answer»

`CH_(3)OH+ CH_(3)- UNDERSET(CH_(3))underset(|)overset(CH_(3))overset(|)C-I`
`CH_(4)+ H_(3)C- underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-OI`
`CH_(3)I+ CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-OH`
`CH_(3)OI+ H_(3)C-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-H`

Solution :When one of the alkyl group is tertiary, the alkyl halide is formed from the tertiary alkyl group.
`underset(underset("ether")("tert-Butymethyl"))(CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-OCH_(3))+HI overset(373 K)RARR underset(underset("alcohol")("Methyl"))(CH_(3)OH)+underset("tert-Butyl iodine")(CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-I)`


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