1.

Complete the following: i. Give the oxidation product of v. Distinguish between allyl alcohol (A) and n-propyl alcohol (B). vi. Complete the following: c. CH_(3)CHO+HC-=CD overset(CH_(3)ONa)(rarr)(A) d. vii. Write the stereochmical products of the following:

Answer»

Solution :
v. `(CH_(2)=CH-CH_(2)OH) (CH_(3)CH_(2)CH_(2)OH)`
Lucas Test
White turbidity immediately cations are resonance stabilised and are as stable as `3^(@) C^(o+)`. They will react as fast as `3^(@)` ALCOHOL with Lucas test, even though they may be `1^(@)` alcohol.
No. REACTION `(1^(@) alcohol)`
b. `H_(2)CrO_(4)`
Blue-GREEN
Blue green
vi. No reaction since the terminal triple bond is absent.

c. `Me-underset(OH)underset(|)(OH)-C-=CD (A)`
(Because bond energy of `C-H` is than `C-D`)
d.
`(B) implies Me-underset(Br)underset(|)(C )=CHC Cl_(3) (anti-Markovnikov's)`



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