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Complete the following reactions and identify the A,B and C in these reaction. (i) CH_(3)-CH_(2)I underset(-NaI) overset(NaCN)(to) (A) underset("Partial hydrolysis")overset(OH^(-))(to) (B) overset(Br_(2)//NaOH)(to) (C) (ii) C_(6)H_(5)N_(2)Cl overset(CuCN)(to) (A) overset(H_(2)"O"//H^(+))(to) (B) overset(NH_(3)//Delta)(to)(C) (iii) CH_(3)-CH_(2)Br overset(KCN)(to)(A)underset(4[H])overset(LiAlH_(4))(to) (B) overset(HNO_(2))(to)(C) (iv) C_(6)H_(5)NO_(2)overset(Sn//HCl)(to)(A)underset(HC//273K)overset(NaNO_(2))(to)(B)overset(H_(2)O//Delta)(to)(C) (v) CH_(3)COOH underset(Delta)overset(NH_(3))(to)(A)underset(Br_(2)//KOH)(to)(B)overset(HNO_(2))(to)(C) |
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Answer» Solution :(i) `underset("Ethyl iodide")(CH_(3)-CH_(2)I-underset(-NaI)overset(NACN)(to) underset((A))underset("Ethyl cyanide")(CH_(3)-CH_(2)CN)underset("Partial hydrlysis")overset(OH^(-))(to) underset((B))underset("Acetamide")(CH_(3)CONH_(2))overset(Br_(2)//NaOH)(to)underset((C))underset("methyl amine")(CH_(3)NH_(2))` (ii) `underset("Benzene diazonium CHLORIDE")(C_(6)H_(5)N_(2)Cl) overset(CuCN)(to) underset((A))underset("Cyano benzene")(C_(6)H_(5)CN)overset(H_(2)"O"//H^(+))(to)underset("benzoic acid")(C_(6)H_(5)COOH)overset(NH_(3)//Delta)(to) underset((C)) underset(Benzamide")(C_(6)H_(5)CONH_(2))` (III) `underset("Ethyl Bromide")(CH_(3)-CH_(2)Br)overset(KCN)(to) underset((A))underset("Ethyl cyanide")(CH_(3)-CH_(2)CN)underset(4[H])overset(LiAlH_(4))(to) `  (iv) `underset("Nitro benzene")(C_(6)H_(5)NO_(2))underset(6[H])overset(Sn//HCl)(to) underset((A))underset("Aniline")(C_(6)H_(5)NH_(2))underset(HCl//273K)overset(NaNO_(2))(to) underset("Benzene diazonium chloride"(B))(C_(6)H_(5)N_(2)^(+)Cl^(-))overset(H_(2)L//Delta)(to) underset("Phenol"(C))(C_(6)H_(5)OH)` (v) `underset("ACETIC acid")(CH_(3)COOH)underset(Delta)overset(NH_(3))(to) underset((A))underset("Acetamide")(CH_(3)CONH_(2))overset(Br_(2)//KOH)(to) underset("Methyl amine"(B))overset(CH_(3)NH_(2))overset(HNO_(2))(to) underset("Methanol " (C))(CH_(3)OH)` |
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