1.

Complete the following reactions : (i) P_(4) + SOCl_(2) rarr (ii) CH_(3)COOH + PCl_(5) rarr

Answer»

Solution :(i) WHITE phosphorus `(P_(4))` reacts with thionyl chloride `(SOCl_(2))` to FORM phosphorus trichloride `(PCl_(3))`
`P_(4) + 8SOCl_(2) rarr 4 PCl_(3) +4 SO_(2) + 2S_(2)Cl_(2)`
(ii) ACETIC acid reacts with phosphorus pentachloride `(PCl_(5))` to form ACETYL chloride
`underset("Acetic acid")(CH_(3)COOH) + PCl_(5) rarr underset("Acetyl chloride")(CH_(3)COCl) + POCl_(3) + HCl`


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