1.

Compound 'A' when treated with conc. HCl and anhydrous ZnCl_(2) at room temperature instantaneouslygives compound 'B' with molecular formula C_(4)H_(9)Cl. When compound 'B' is further boiled with aqueous KOH, it gives back compound 'A'. 'A' overset(HCl+"anhydrous Zn"Cl_(2)) to underset([C_(4)H_(9)Cl]) B underset(Delta)overset(aq. KOH) to 'A' Identify the compound 'A' and 'B'.

Answer»

`CH_(3)-CH_(2)-CH_(2)-CH_(2)-OH , CH_(3)-CH_(2)-CH_(2)-CH_(2)-CL`
`CH_(3)-underset(CH_(3))underset(|)OVERSET(CH_(3))overset(|)C-OH, CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-Cl`
`CH_(3)-underset(CH_(3))underset(|)CH-CH_(2)-OH, CH_(3)-underset(CH_(3))underset(|)CH-CH_(2)-Cl`
`CH_(3)-CH_(2)-overset(CH_(3))overset(|)CH-OH, CH_(3)-CH_(2)-overset(CH_(3))overset(|)CH-Cl`

ANSWER :B


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