1.

Compound 'X' containing chlorine, on treatment with NH_(3) gives a solid 'Y' which is free from chlorine. (Y) analysed as C=49.31%,H=9.59% and N=19.18% and reacts with Br_(2) and caustic soda to give a basic compound (Z),(Z) reacts with HNO_(2) to give ethanol. Suggest structure of (X), (Y) and (Z).

Answer»


Answer :EMPIRICAL FORMULA of (Y) is `C_(3)H_(7)NO`
CH_(3)CH_(2)NH_(2)`
`CH_(3)CH_(2)COCl+NH_(3)rarr2 CH_(3)CH_(2)CONH_(2)`


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