1.

Compund (A), C_(5)H_(11)NO is not soluble in cold alkaline or acidic solutions. When (A) is refluxed in NaOH solution, a gas (B) is evolved and salt (C) is formed. Acetyl chloride reacts with (B) to give (D), (C_(4)H_(9)NO). (B) reacts with HNO_(2) to give a yellow oil (E). Give structures of (A) to (E) with reason.

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Answer :(A) `=CH_(3)CH_(2)CON(CH_(3))_(2),B=(CH_(3))_(2)NH,C=CH_(3)CH_(2)COONa,D=CH_(3)CON(CH_(3))_(2)` and `E=(CH_(3))_(2)N-N=O


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