1.

Concentrated aqueous sulphuric acid is 98% H_(2)SO_(4) by mass and has a density of "1.80 g mL"^(-1). Volume of the acid required to make one litre of 0.1 M H_(2)SO_(4) solution is

Answer»

5.55 mL
11.10 mL
16.65 mL
22.20 mL

Solution :`98% H_(2)SO_(4)` by mass means `98 g _(2)SO_(4)` PRESENT in 100 g of the solution,
i.e., 100/1.80 mL = 55.5 mL
Also `"98 g "H_(2)SO_(4)="1 mole "H_(2)SO_(4)`
`therefore"Molarity of 98% "H_(2)SO_(4)` solution
`=(1)/(55.5)xx"1000 mol L"^(-1)`
Now, `M_(1)V_(1)=M_(2)V_(2).`
HENCE, `(1000)/(55.5)MxxV_(1)="1000 mL"xx0.1M`
`"or"V_(1)=5.55mL`


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