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Consider the following equations for cell reaction: `A+BhArrC+D` ….(`1`) and `2A+BhArr2C+2D` …(`2`) How are `E_(cell)^(@)` for equations (`1`) and (`2`) are related? What is relation between two equilibrium constants? |
Answer» `E_(cell)^(@)` for eq. (`1`) and (`2`) is same as it does not depend upon stoichiometry of chemical equation. Also `K_(1)=([C][D])/([A][B])`, `K_(2)=([C]^(2)[D]^(2))/([A]^(2)[B]^(2))` `:. K_(1)=sqrt(K_(2))` |
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