1.

Consider the following reaction at certain temperature : H_(2) (g) + Cl_(2) (g) hArr 2HCl (g) The mixing of 1 mol of H_(2) with 4 moles of Cl_(2) from x moles of HCl at equilibrium. If we add 5 moles of H_(2) at equilibrium then another 2x moles of HCl are produced. Then find K_("eq") for above reaction.

Answer»


Solution :`{:(,H_(2) (g),+,Cl_(2) (g),hArr,2HCl (g),,),("INITIALLY",1,,4,,-,,),("Equilibrium",1 - (X)/(2),,4 - (x)/(2),,x,,),("New Equilibrium",6 - (3x)/(2),,4 - (3x)/(2),,3x,["After adding 5 moles of" H_(2)],):}`
`K_(C) = (x^(2))/((1 - (x)/(2))(4 - (x)/(2))) = ((3x)^(2))/((4 - (3x)/(2)) (6 - (3x)/(2)))`
`x = 1.6`
`K_(eq) = (1.6 xx 1.6)/((1 - (1.6)/(2))(4 - (1.6)/(2)))`
`K_(eq) = 4`


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