Consider the following reaction : Na_(2)SO_(3) + S overset("Boiling")underset(H_(2)O) to X (Colourless liquid) AgBr overset("Excess")to Y (Soluble complex) X + Cl_(2) + H_(2)O (l) overset("Boiling")underset(H_(2)O)to Z + HCl The (X), (Y) and (Z) are respectively

Consider the following reaction : Na_(2)SO_(3) + S overset("Boiling")

1.	Consider the following reaction : Na_(2)SO_(3) + S overset("Boiling")underset(H_(2)O) to X (Colourless liquid) AgBr overset("Excess")to Y (Soluble complex) X + Cl_(2) + H_(2)O (l) overset("Boiling")underset(H_(2)O)to Z + HCl The (X), (Y) and (Z) are respectively
Answer» `Na_(2)S_(4)O_(6), [Ag(S_(2)O_(3))_(2)]^(2-), NaHSO_(4)` `Na_(2)S_(2)O_(3), [Ag(S_(2)O_(3))_(2)]^(3-), NaHSO_(4)` `Na_(2)S_(4)O_(6), [Ag(S_(2)O_(3))_(2)]^(3-), NaHSO_(4)` `Na_(2)S_(3)O_(3), [Ag(S_(2)O_(3))_(2)]^(3-), Na_(2)SO_(4)` Solution :`Na_(2)S_(2)O_(3) + S OVERSET("Boiling")underset(H_(2)O)to Na_(2)S_(2)O_(3)[X]` `AgBr + 2Na_(2)S_(2)O_(3) to underset("SOLUBLE complex Y")(Na_(3)[Ag(S_(2)O_(3))_(2)]) + NaBr` `Na_(2)S_(2)O_(3) + 4Cl_(2) + 5H_(2)O overset("Boiling")to 2NaHSO_(4) + 8HCl`