1.

Consider the following redox reaction: 2lrCl_(6)^(3-)+3HCOOHto2lr+3CO_(2)+12Cl^(-)+6H^(+) Given: CO_(2)+2H_(3)O^(+)+2etoHCOOH+2H_(2)O""E^(@)=-0.20V lrCl_(6)^(3-)+3etolr+6Cl^(-)""E^(@)=0.77V (a). Determine standard state emf of cell. (b). Is this reaction thermodynamically spontaneous as written? Briefly explain.

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SOLUTION :N


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