1.

Consider the following statements and arrange in the order of true/false as given in the codes. S_1:The hydrogen bond in salt, KHF_2 is stronger than that in gasous HF. S_2 :The dipole moment of CH_3F is greater than that of CH_3Cl. S_3:sp^2 hybrid orbitals have equals s and p character. S_4:Two types of bond present in B_2H_6 are covalent and three centre-two electrons bonds.

Answer»

<P>TTFF
TFFT
FFFT
F F T T

Solution :`S_1:KHF_2,F-H-F , DeltaH~~-212 kJ mol^(-1)`, involves resonance H-F-`hArr` H-F-H
HF,F-`H_F` : `DeltaH~~-28.6 kJ mol^(-1)`
`S_2: CH_3ClgtCH_3F` due to large charge SEPARATION in`CH_3Cl` as compared to that in `CH_3F`
`CH_3F,mu=1.85 D,CH_3Cl, mu=1.87 D`
`S_3`: In `sp^2` HYBRID orbitals character is 33.3% and p character is 66.6%
`S_4`:
Terminal B-H BOND are covalent while bridging B-H bonds are three centre-two ELECTRON bonds.


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