Consider the following statements : statement-1: [Cr(NH_(3))_(6)]^(3+)]^(3+) is an inner orbital complex with crystal field stabilization energy complex with crystal field stabilization energy equal to -1.2 Delta_(0). Statement -2: The complex formed by joining the CN^(-) ligands to Fe^(3+) ion has theoretical value of 'spin only' magnetic moment equal to 1.73 BM. Statement-3: Na_(2)S+Na_(2) [Fe(CN)_(5)NO]to Na_(4)[Fe(CN)_(5)NOS], In reactant and product the oxidation states of iron are same and arrange in the order of true/false.

Consider the following statements : statement-1: [Cr(NH_(3))_(6)]^(3+

1.	Consider the following statements : statement-1: [Cr(NH_(3))_(6)]^(3+)]^(3+) is an inner orbital complex with crystal field stabilization energy complex with crystal field stabilization energy equal to -1.2 Delta_(0). Statement -2: The complex formed by joining the CN^(-) ligands to Fe^(3+) ion has theoretical value of 'spin only' magnetic moment equal to 1.73 BM. Statement-3: Na_(2)S+Na_(2) [Fe(CN)_(5)NO]to Na_(4)[Fe(CN)_(5)NOS], In reactant and product the oxidation states of iron are same and arrange in the order of true/false.
Answer» FTF TTF TTT FFF Solution :`[CR(NH_(3))_(6)]^(3+) implies d^(3) , t_(2 g )^( 2 ,2 , 1) EG^(0 , 0)` CFSE = `-0.4 XX 3 Delta_(0) = -1.2 Delta_(0)`.