1.

Consider the following system. Three different aqueous solution each having volume 100 ml are taken are kept in contact as shown. After sufficient time (Consider temp constant & 100% dissociation of strong electrolyte )

Answer»

Volume of urea solution will be `100/3` ML.
Volume of `AlCl_3` solution will be `400/3` ml.
There will be no change in volume of KCl solution
Volume of both KCl and `AlCl_2` solutions will increase.

Solution :After SUFFICIENT time osmotic pressure of all solution will become same.
as T is same i.e. molar concentration should be same, for this ratio of volume should be the same as that of ratio moles.
`{:("Urea",:,KCl,:,AlCl_3),(20 m "moles", " " ,30 m "moles", " " ,40 m "moles"):}`
Total volume (300 ml) should be divided in 2:3:4
`V_("urea")=2/9xx300=200/3 ml`
`V_(KCl)=3/9xx300=100 ml`
`V_(AlCl_3)=4/9xx300=400/3`ml


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