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Consider the following two equilibrium established together in a closed container `A(s)hArr2B(g)+3C(g) , K_(P_(1)` `A(s)hArr3D(g) , K_(P_(2)` Starting with only `A(s)`, molar ratio of `B(g)` & `D(g)` at equilibrium is found to be in a ratio `1:6` determine `(K_(P_(2)))/(8K_(P_(1)))`

Answer» Correct Answer - 8
`P_(B):P_(D)=1:6` Let the partial at pressure of `B` eq. be `P_(0)`
`K_(p_(1))=(P_(0))^(2)((3P_(0))/(2))^(3)`
`K_(p_(2))=(6P_(0))^(3)`
`(K_(p_(2)))/(K_(p_(1)))=(6^(3))/(((3)/(2))^(3))=64`
`(K_(p_(2)))/(8K_(p_(1)))=(64)/(8)=8`


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