Consider two chemical reactions. HCOOH_((l))+H_(2)SO_(4(l)) to CO_((g)) +H_(2)SO_(4). H_(2)O_((hq)) H_(2)C_(2)O_(4(l)) +H_(2)SO_(4(l))to CO_((g)) +CO_(2(g))+H_(2)SO_(4).H_(2)O_((hq)) Different mixtures HCOOH & H_(2)C_(2)O_(4) are taken & reacted with H_(2)SO_(4(l)) & gases produced are passed through KOH. select the option (s) in which correct combination of composition of mixture & percentage volume contraction on passing through KOH is mentioned.

Consider two chemical reactions. HCOOH_((l))+H_(2)SO_(4(l)) to CO_((g

1.	Consider two chemical reactions. HCOOH_((l))+H_(2)SO_(4(l)) to CO_((g)) +H_(2)SO_(4). H_(2)O_((hq)) H_(2)C_(2)O_(4(l)) +H_(2)SO_(4(l))to CO_((g)) +CO_(2(g))+H_(2)SO_(4).H_(2)O_((hq)) Different mixtures HCOOH & H_(2)C_(2)O_(4) are taken & reacted with H_(2)SO_(4(l)) & gases produced are passed through KOH. select the option (s) in which correct combination of composition of mixture & percentage volume contraction on passing through KOH is mentioned.
Answer» Molar RATIO HCOOH:`H_(2)C_(2)O_(4) = 1:1` % VOLUME contraction `=100/3%` Molar ratio HCOOH :`H_(2)C_(2)O_(4) =1:3` % volume contraction `=300/7%` Molar ratio HCOOH :`H_(2)C_(2)O_(4) =2:3` % volume contraction `=300/8%` Molar ratio HCOOH : `H_(2)C_(2)O_(4)=3:5` % volume contraction `=1000/13 %` Answer :ABC