1.

[Cr(NH_(3))_(6)]^(3+) is paramagnetic while [Ni(CN)_(4)]^(2-) is diamagnetic . Explainwhy?

Answer»

Solution :`Cr(24) : [Ar]4s^(1)3D^(5)`
`Cr^(3+)(24) : [Ar]4s^(0)3d^(5)`
`[Cr(NH_(3))_(6)]^(3+)`
It is PARAMAGNETIC DUE to the presence of unpaired electrons.

It has a square planar STRUCTURE, and it is diamagnetic due to the absence of unpaired electrons.


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