1.

(d) Estimation of phosphorous: A known mass of compound is heated with fuming HNO_(3) or sodiumperoxide (Na_(2)O_(2)) in Carius tube which converts phosphorrous to H_(3)PO_(4) . Magnesia mixture (MgCL_(2) + NH_(4)Cl) is then added, which gives the precipitate of magnesium ammonium phosphate (MgNH_(4).PO_(4)) which on heatinggives magnesium pyrophosphate (Mg_(2)P_(2)O_(7)) , which is weighed. An organic compound has 6.2 % of phosphorus. On sequence of reaction, the phosphorous present in 10 gm of organic compound is converted of Mg_(2)P_(2)O_(7) . Find the weight of Mg_(2)P_(2)O_(7) formed.

Answer»

2.22 gm
10.0 gm
4.44 gm
1.11 gm

Answer :A


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