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Define and explain the term, enthalpy or heat of reaction. |
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Answer» <P> Solution :Enthalpy or HEAT of reaction : The enthalpy of a chemicalreaction is the difference between the sum of the enthalpies of products and that of the reactants with every substance in a definite physicalstate and in the amounts (moles) represented by the coefficients in the BALANCED equation.Explanation : Consider the following GENERAL reaction, `aA + bB to cC +dD` The heat of the reaction `DeltaH` is the difference in sum of enthalpies ofproducts and sum of enthalpies of reactants. `therefore DeltaH = sum H_("products") - sum H_("reactants")` ` =[CH_(c) +dH_(D)] - [aH_(A)+bH_(B)]` ` =sum""_(p)H - sum""_(R)H` where H represents enthalpy of the substance. For endothermic reaction, `DeltaH` is positive,`(DeltaH gt 0)` For exothermic reaction, `DeltaH` is negative `(DeltaHlt 0)`. |
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