1.

Describe for any two of the following complex ions, the type of hybridisation, shape and magnetic property : [Fe(H_(2)O)_(6)]^(2+)

Answer»

Solution :`[Fe(H_(2)O)_(6)]^(2+)`
Electronic configuration of Fe : [AR] `4s^(2) 3d^(6)`
Electronic configuration of `Fe^(2+) : [Ar] 4s^(0) 3d^(6)`
`H_(2)O` is WEAK field ligand. It does not cause pairing of electrons.
`[Fe(H_(2)O)_(6)]^(2+)` Electrons DONATED by the ligands
It has `sp^(3)d^(2)` hybridisation with octahedral shape. It is PARAMAGNETIC due to the presence of unpaired electrons.


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