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Describe the three steps involved in the leaching of bauxite to get pure alumina (equations not expected). |
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Answer» Solution :Baeyer.s process is one of the methods used. (a) This method involves the digesting or powdered bauxite ore with concentrated NaOH at 473 - 523 K and 35 - 36 bar pressure. `Al_2O_3` is leached out as sodium aluminate (and `SiO_2` too as sodium silicate) leaving the impurities behind, `UNDERSET("bauxite")(Al_2O_3(S)+2NaOH(aq)+3H_2O(I))tounderset("Sodium aluminate")(2Na[Al(OH)_4](aq))` (B) Now `CO_2` gas is PASSED through the solution and a small amount of freshly prepared hydrated aluminium oxide is also added in order in induce the precipitation. `2Na[Al(OH)_4](aq)+CO_2(aq)tounderset("Hydrated aluminium oxide ppt")Al_2O_3.xH_2O(s)+2NaHCO_2(aq)` (c) The impurities of silica remain in the solution and the precipitate. formed is-filtered, washed, dried and ignited to produce pure alumina. `Al_2O_3,xH_2O(s)tooverset(1470K)toAl_2O_3(s)+xH_2O(g)` |
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