1.

Dialkyl ethers react with very few reagents other acids. The only reactive sites that molecules of a dialkyl ether has to another reactive substance are the C H bonds of the alkyl groups and the O group of the ether linkage. Heating dialkyl ethers with very strong acids. (HI, HBr, and H_(2)SO_(4)) causes them to undergo reactions in which the carbon-oxygen bond breaks. When mixed ethers are used, the alcohol and alkyl iodide that form depend on the nature of the alkyl groups. Mechanism is by S_(N)^(2) reaction or S_(N)^(1). What is the coorect order of reactivity towards conc. HI assuming S_(N)^(2) type cleavage?

Answer»

`I GT IV gt III gt I`
`I gt III gt IV gt II`
`II gt I gt IV gt III`
`IV gt II gt III gt I`

Answer :B


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