1.

Equal quantities of electricity are passed through 3 votameters containing FeSO_(4),Fe_(2)(SO_(4))_(2) and Fe(NO_(3))_(3). Cosider the following statements (A) The amounts of iron deposited I FeSO_(4) and Fe_(2)(SO_(4))_(3) are equal (B) The amount of iron deposited in Fe(NO_(3))_(2) is 2//3^(rd) of the amount deposited in FeSO_(4) (C) The amount of iron deposited in Fe_(2)(SO_(4))_(3) and Fe(NO_(3))_(3) are equal

Answer»

(A) is CORRECT
(B) is correct
(C) is correct
Both (A) and (B) are correct

Solution :Suppose 2F of ELECTRICITY passed through `FeSO_(4),Fe_(2)(SO_(4))_(3) and Fe(NO_(3))_(3)` solution.
`FeSO_(4)toFe^(2+)+SO_(4)^(2-)`
`Fe^(2+)+underset(2F)(2e^(-))tounderset("1 mole")(Fe(S))`
`Fe_(2)(SO_(4))_(3)to2Fe^(3+)3SO_(4)^(2-)`
`Fe^(3+)+underset(3F)(3e^(-))to underset(1" mole")(Fe(S))`
`Fe(NO_(3))_(3)toFe_(3+)^(-)`
`Fe^(3+)+underset(3F)(3e^(-))tounderset("1 mole")(Fe(S))`
`therefore2F` will give`=(2)/(3)` mole


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